Bioconcentration of the anionic surfactant linear alkylbenzene sulfonate (LAS) in the marine shrimp Palaemonetes varians: A radiotracer study     

Florent Renaud  Michel Warnau  François Oberhänsli  Jean-Louis Teyssié  Ali Temara  Claude Rouleau  Marc Metian 《Marine pollution bulletin》2014

Uptake and depuration kinetics of dissolved [¹⁴C]C₁₂-6-linear alkylbenzene sulfonate (LAS) were determined in the shrimp Palaemonetes varians using environmentally relevant exposure concentration. The shrimp concentrated LAS from seawater with a mean BCF value of 120 L kg⁻¹ after a 7-day exposure. Uptake biokinetics were best described by a saturation model, with an estimated BCF_ss, of 159 ± 34 L kg⁻¹, reached after 11.5 days. Shrimp weight influenced significantly BCF value with smaller individuals presenting higher affinity to LAS. To the light of a whole body autoradiography, major accumulation of LAS occurred in the cephalothorax circulatory system (gills, heart, hepatopancreas) and ocular peduncle, but not in the flesh, limiting potential transfer to human consumers. LAS depuration rate constant value of the shrimp was 1.18 ± 0.08 d⁻¹ leading to less than 1% of remaining LAS in its tissues after 8 days of depuration.  相似文献   

Exhumation and incision history of the Lahul Himalaya, northern India, based on (U–Th)/He thermochronometry and terrestrial cosmogenic nuclide methods     

Byron Adams  Craig Dietsch  Lewis A. Owen  Marc W. Caffee  James Spotila  William C. Haneberg 《Geomorphology》2009,107(3-4):285-299

Low-temperature apatite (U–Th)/He (AHe) thermochronology on vertical transects of leucogranite stocks and ¹⁰Be terrestrial cosmogenic nuclide (TCN) surface exposure dating on strath terraces in the Lahul Himalaya provide a first approximation of long-term (10⁴–10⁶ years) exhumation rates for the High Himalayan Crystalline Series (HHCS) for northern India. The AHe ages show that exhumation of the HHCS in Lahul from shallow crustal levels to the surface was ~ 1–2 mm/a and occurred during the past ~ 2.5 Ma. Bedrock exhumation in Lahul fits into a regional pattern in the HHCS of low-temperature thermochronometers yielding Plio-Pleistocene ages. Surface exposure ages of strath terraces along the Chandra River range from ~ 3.5 to 0.2 ka. Two sites along the Chandra River show a correlation between TCN age and height above the river level yielding maximum incision rates of 12 and 5.5 mm/a. Comparison of our AHe and surface exposure ages from Lahul with thermochronometry data from the fastest uplifting region at the western end of the Himalaya, the Nanga Parbat syntaxis, illustrates that there are contrasting regions in the High Himalaya where longer term (10⁵–10⁷ years) erosion and exhumation of bedrock substantially differ even though Holocene rates of fluvial incision are comparable. These data imply that the orogen's indenting corners are regions where focused denudation has been stable since the mid-Pliocene. However, away from these localized areas where there is a potent coupling of tectonic and surface processes that produce rapid uplift and denudation, Plio-Pleistocene erosion and exhumation can be characterized by disequilibrium, where longer term rates are relatively slower and shorter term fluvial erosion is highly variable over time and distance. The surface exposure age data reflect differential incision along the length of the Chandra River over millennial time frames, illustrate the variances that are possible in Himalayan river incision, and highlight the complexity of Himalayan environments.  相似文献   

The timing and extent of the eruption of the Siberian Traps large igneous province: Implications for the end-Permian environmental crisis     

Marc K. Reichow  M.S. Pringle  A.I. Al'Mukhamedov  M.B. Allen  V.L. Andreichev  M.M. Buslov  C.E. Davies  G.S. Fedoseev  J.G. Fitton  S. Inger  A.Ya. Medvedev  C. Mitchell  V.N. Puchkov  I.Yu. Safonova  R.A. Scott  A.D. Saunders 《Earth and Planetary Science Letters》2009,277(1-2):9-20

We present new high-precision ⁴⁰Ar/³⁹Ar ages on feldspar and biotite separates to establish the age, duration and extent of the larger Siberian Traps volcanic province. Samples include basalts and gabbros from Noril'sk, the Lower Tunguska area on the Siberian craton, the Taimyr Peninsula, the Kuznetsk Basin, Vorkuta in the Polar Urals, and from Chelyabinsk in the southern Urals. Most of the ages, except for those from Chelyabinsk, are indistinguishable from those found at Noril'sk. Cessation of activity at Noril'sk is constrained by a ⁴⁰Ar/³⁹Ar age of 250.3 ± 1.1 Ma for the uppermost Kumginsky Suite.The new ⁴⁰Ar/³⁹Ar data confirm that the bulk of Siberian volcanism occurred at 250 Ma during a period of less than 2 Ma, extending over an area of up to 5 million km². The resolution of the data allows us to confidently conclude that the main stage of volcanism either immediately predates, or is synchronous with, the end-Permian mass extinction, further strengthening an association between volcanism and the end-Permian crisis. A sanidine age of 249.25 ± 0.14 Ma from Bed 28 tuff at the global section and stratotype at Meishan, China, allows us to bracket the P–Tr boundary to 0.58 ± 0.21 myr, and enables a direct comparison between the ⁴⁰Ar/³⁹Ar age of the Traps and the Permo–Triassic boundary section.Younger ages (243 Ma) obtained for basalts from Chelyabinsk indicate that volcanism in at least the southern part of the province continued into the Triassic.  相似文献   

Study of water tension differences in heterogeneous sandy soils using surface ERT   总被引：1，自引：0，他引：1  

Marc Descloitres  Olivier Ribolzi  Yann Le Troquer  Jean Pierre Thibaux 《Journal of Applied Geophysics》2008,64(3-4):83-98

Herbaceous vegetation in the Sahel grows almost exclusively on sandy soils which preferentially retain water through infiltration and storage. The hydrological functioning of these sandy soils during rain cycles is unknown. One way to tackle this issue is to spatialize variations in water content but these are difficult to measure in the vadose zone. We investigated the use of Electrical Resistivity Tomography (ERT) as a technique for spatializing resistivity in a non-destructive manner in order to improve our knowledge of relevant hydrological processes. To achieve this, two approaches were examined. First, we focused on a possible link between water tension (which is much easier to measure in the field by point measurements than water content), and resistivity (spatialized with ERT). Second, because ERT is affected by solution non-uniqueness and reconstruction smoothing, we improved the accuracy of ERT inversion by comparing calculated solutions with in-situ resistivity measurements. We studied a natural microdune during a controlled field experiment with artificial sprinkling which reproduced typical rainfall cycles. We recorded temperature, water tension and resistivity within the microdune and applied surface ERT before and after the 3 rainfall cycles. Soil samples were collected after the experiment to determine soil physical characteristics. An experimental relationship between water tension and water content was also investigated. Our results showed that the raw relationship between calculated ERT resistivity and water tension measurements in sand is highly scattered because of significant spatial variations in porosity. An improved correlation was achieved by using resistivity ratio and water tension differences. The slope of the relationship depends on the soil solution conductivity, as predicted by Archie's law when salted water was used for the rain simulation. We found that determining the variations in electrical resistivity is a sensitive method for spatializing the differences in water tension which are directly linked with infiltration and evaporation/drainage processes in the vadose zone. However, three factors complicate the use of this approach. Firstly, the relation between water tension and water content is generally non-linear and dependent on the water content range. This could limit the use of our site-specific relations for spatializing water content with ERT through tension. Secondly, to achieve the necessary optimization of ERT inversion, we used destructive resistivity measurements in the soil, which renders ERT less attractive. Thirdly, we found that the calculated resistivity is not always accurate because of the smoothing involved in surface ERT data inversion. We conclude that further developments are needed into ERT image reconstruction before water tension (and water content) can be spatialized in heterogeneous sandy soils with the accuracy needed to routinely study their hydrological functioning.  相似文献   

Array performances for ambient vibrations on a shallow structure and consequences over <Emphasis Type="Italic">V</Emphasis><Subscript><Emphasis Type="Italic">s</Emphasis></Subscript> inversion     

Marc Wathelet  Denis Jongmans  Matthias Ohrnberger  Sylvette Bonnefoy-Claudet 《Journal of Seismology》2008,12(1):1-19

Valuable information about one-dimensional soil structures can be obtained by recording ambient vibrations at the surface, in which the energy contribution of surface waves predominates over the one of other types of waves. The dispersion characteristics of surface waves allow the retrieval of the shear-wave velocity as a function of depth. Microtremor studies are usually divided in two stages: deriving the dispersion (or auto-correlation) curve from the recorded signals and inverting it to obtain the site velocity profile. The possibility to determine the dispersion curve over the adequate frequency range at one site depends on the array aperture and on the wavefield spectra amplitude that can be altered by filtering effects due to the ground structure. Microtremors are usually recorded with several arrays of various apertures to get the spectral curves over a wide frequency band, and different methods also exist for processing the raw signals. With the objective of defining a strategy to achieve reliable results for microtremor on a shallow structure, we analyse synthetic ambient vibrations (vertical component) simulated with 333 broadband sources for a 25-m deep soil layer overlying a bedrock. The first part of our study is focused on the determination of the reliable frequency range of the spectral curves (dispersion or auto-correlation) for a given array geometry. We find that the wavenumber limits deduced from the theoretical array re sponse are good estimates of the valid spectral curve range. In the second part, the spectral curves are calculated with the three most popular noise-processing techniques (frequency–wavenumber, high-resolution frequency–wavenumber and spa tial auto-correlation methods) and inverted indi vidually in each case. The inversions are performed with a tool based on the neighbour hood algorithm that offers a better estimation of the global uncertainties than classical linearised methods, especially if the solution is not unique. Several array apertures are necessary to construct the dispersion (auto-correlation) curves in the appropriate frequency range. Considering the final velocity profiles, the three tested methods are almost equivalent, and no significant advantage was found for one particular method. With the chosen model, all methods exhibit a penetration limited to the bedrock depth, as a consequence of the filtering effect of the ground structure on the vertical component, which was observed in numerous shallow sites.  相似文献   

Isothermal compression of an eclogite from the Western Gneiss Region (Norway)     

Martin Simon  Pavel Pitra  Philippe Yamato  Marc Poujol 《Journal of Metamorphic Geology》2023,41(1):181-203

In the Western Gneiss Region in Norway, mafic eclogites form lenses within granitoid orthogneiss and contain the best record of the pressure and temperature evolution of this ultrahigh-pressure (UHP) terrane. Their exhumation from the UHP conditions has been extensively studied, but their prograde evolution has been rarely quantified although it represents a key constraint for the tectonic history of this area. This study focused on a well-preserved phengite-bearing eclogite sample from the Nordfjord region. The sample was investigated using phase-equilibrium modelling, trace-element analyses of garnet, trace- and major-element thermobarometry and quartz-in-garnet barometry by Raman spectroscopy. Inclusions in garnet core point to crystallization conditions in the amphibolite facies at 510–600°C and 11–16 kbar, whereas chemical zoning in garnet suggests growth during isothermal compression up to the peak pressure of 28 kbar at 600°C, followed by near-isobaric heating to 660–680°C. Near-isothermal decompression to 10–14 kbar is recorded in fine-grained clinopyroxene–amphibole–plagioclase symplectites. The absence of a temperature increase during compression seems incompatible with the classic view of crystallization along a geothermal gradient in a subduction zone and may question the tectonic significance of eclogite facies metamorphism. Two end-member tectonic scenarios are proposed to explain such an isothermal compression: Either (1) the mafic rocks were originally at depth within the lower crust and were consecutively buried along the isothermal portion of the subducting slab or (2) the mafic rocks recorded up to 14 kbar of tectonic overpressure at constant depth and temperature during the collisional stage of the orogeny.  相似文献